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Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate

In the asymmetric unit of the title compound, C(19)H(16)O(2), there are two symmetry-independent mol­ecules (A and B) that differ in the conformation of the ester eth­oxy group. In the crystal, the mol­ecules form inversion dimers via pairs of C—H⋯O inter­actions. Within the dimers, the anthracenyl...

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Detalles Bibliográficos
Autores principales: Bugenhagen, Bernhard, Al Jasem, Yosef, Hindawi, Bassam al, Al Rawashdeh, Nathir, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588290/
https://www.ncbi.nlm.nih.gov/pubmed/23476390
http://dx.doi.org/10.1107/S1600536812051033
Descripción
Sumario:In the asymmetric unit of the title compound, C(19)H(16)O(2), there are two symmetry-independent mol­ecules (A and B) that differ in the conformation of the ester eth­oxy group. In the crystal, the mol­ecules form inversion dimers via pairs of C—H⋯O inter­actions. Within the dimers, the anthracenyl units have inter­planar distances of 0.528 (2) and 0.479 (2) Å for dimers of mol­ecules A and B, respectively. Another short C—H⋯O contact between symmetry-independent dimers links them into columns parallel to [10-1]. These columns are arranged into (111) layers and there are π–π stacking inter­actions [centroid–centroid distances = 3.6446 (15) and 3.6531 (15) Å] between the anthracenyl units from the neighbouring columns. In addition, there are C—H⋯π inter­actions between the anthracenyl unit of dimers A and dimers B within the same column.