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Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate
In the asymmetric unit of the title compound, C(19)H(16)O(2), there are two symmetry-independent molecules (A and B) that differ in the conformation of the ester ethoxy group. In the crystal, the molecules form inversion dimers via pairs of C—H⋯O interactions. Within the dimers, the anthracenyl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588290/ https://www.ncbi.nlm.nih.gov/pubmed/23476390 http://dx.doi.org/10.1107/S1600536812051033 |
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author | Bugenhagen, Bernhard Al Jasem, Yosef Hindawi, Bassam al Al Rawashdeh, Nathir Thiemann, Thies |
author_facet | Bugenhagen, Bernhard Al Jasem, Yosef Hindawi, Bassam al Al Rawashdeh, Nathir Thiemann, Thies |
author_sort | Bugenhagen, Bernhard |
collection | PubMed |
description | In the asymmetric unit of the title compound, C(19)H(16)O(2), there are two symmetry-independent molecules (A and B) that differ in the conformation of the ester ethoxy group. In the crystal, the molecules form inversion dimers via pairs of C—H⋯O interactions. Within the dimers, the anthracenyl units have interplanar distances of 0.528 (2) and 0.479 (2) Å for dimers of molecules A and B, respectively. Another short C—H⋯O contact between symmetry-independent dimers links them into columns parallel to [10-1]. These columns are arranged into (111) layers and there are π–π stacking interactions [centroid–centroid distances = 3.6446 (15) and 3.6531 (15) Å] between the anthracenyl units from the neighbouring columns. In addition, there are C—H⋯π interactions between the anthracenyl unit of dimers A and dimers B within the same column. |
format | Online Article Text |
id | pubmed-3588290 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35882902013-03-08 Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate Bugenhagen, Bernhard Al Jasem, Yosef Hindawi, Bassam al Al Rawashdeh, Nathir Thiemann, Thies Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(19)H(16)O(2), there are two symmetry-independent molecules (A and B) that differ in the conformation of the ester ethoxy group. In the crystal, the molecules form inversion dimers via pairs of C—H⋯O interactions. Within the dimers, the anthracenyl units have interplanar distances of 0.528 (2) and 0.479 (2) Å for dimers of molecules A and B, respectively. Another short C—H⋯O contact between symmetry-independent dimers links them into columns parallel to [10-1]. These columns are arranged into (111) layers and there are π–π stacking interactions [centroid–centroid distances = 3.6446 (15) and 3.6531 (15) Å] between the anthracenyl units from the neighbouring columns. In addition, there are C—H⋯π interactions between the anthracenyl unit of dimers A and dimers B within the same column. International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588290/ /pubmed/23476390 http://dx.doi.org/10.1107/S1600536812051033 Text en © Bugenhagen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bugenhagen, Bernhard Al Jasem, Yosef Hindawi, Bassam al Al Rawashdeh, Nathir Thiemann, Thies Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title | Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title_full | Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title_fullStr | Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title_full_unstemmed | Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title_short | Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate |
title_sort | ethyl (e)-3-(anthracen-9-yl)prop-2-enoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588290/ https://www.ncbi.nlm.nih.gov/pubmed/23476390 http://dx.doi.org/10.1107/S1600536812051033 |
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