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1-(4-Nitrophenyl)-1H-imidazol-3-ium chloride
In the title salt, C(9)H(8)N(3)O(2) (+)·Cl(−), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic molecules through N—H⋯Cl hydrogen bonds, forming chains that run diagonally ac...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588291/ https://www.ncbi.nlm.nih.gov/pubmed/23476377 http://dx.doi.org/10.1107/S1600536812050878 |
Sumario: | In the title salt, C(9)H(8)N(3)O(2) (+)·Cl(−), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic molecules through N—H⋯Cl hydrogen bonds, forming chains that run diagonally across the bc face, which compliment strong C—H⋯O hydrogen bonds between neighbouring molecules. These chains are connected to adjacent chains through two weak C—H⋯Cl interactions, resulting in hydrogen-bonded sheets extending along the b and c axes. The absolute structure of the title compound was determined using a Flack x parameter of 0.00 (6) and a Hooft y parameter of 0.03 (2). |
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