1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride

In the title salt, C(9)H(8)N(3)O(2) (+)·Cl(−), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic mol­ecules through N—H⋯Cl hydrogen bonds, forming chains that run diagonally ac...

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Detalles Bibliográficos
Autores principales: Ibrahim, Halliru, Bala, Muhammad D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588291/
https://www.ncbi.nlm.nih.gov/pubmed/23476377
http://dx.doi.org/10.1107/S1600536812050878
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author Ibrahim, Halliru
Bala, Muhammad D.
author_facet Ibrahim, Halliru
Bala, Muhammad D.
author_sort Ibrahim, Halliru
collection PubMed
description In the title salt, C(9)H(8)N(3)O(2) (+)·Cl(−), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic mol­ecules through N—H⋯Cl hydrogen bonds, forming chains that run diagonally across the bc face, which compliment strong C—H⋯O hydrogen bonds between neighbouring mol­ecules. These chains are connected to adjacent chains through two weak C—H⋯Cl inter­actions, resulting in hydrogen-bonded sheets extending along the b and c axes. The absolute structure of the title compound was determined using a Flack x parameter of 0.00 (6) and a Hooft y parameter of 0.03 (2).
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spelling pubmed-35882912013-03-08 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride Ibrahim, Halliru Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(9)H(8)N(3)O(2) (+)·Cl(−), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic mol­ecules through N—H⋯Cl hydrogen bonds, forming chains that run diagonally across the bc face, which compliment strong C—H⋯O hydrogen bonds between neighbouring mol­ecules. These chains are connected to adjacent chains through two weak C—H⋯Cl inter­actions, resulting in hydrogen-bonded sheets extending along the b and c axes. The absolute structure of the title compound was determined using a Flack x parameter of 0.00 (6) and a Hooft y parameter of 0.03 (2). International Union of Crystallography 2012-12-19 /pmc/articles/PMC3588291/ /pubmed/23476377 http://dx.doi.org/10.1107/S1600536812050878 Text en © Ibrahim and Bala 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ibrahim, Halliru
Bala, Muhammad D.
1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title_full 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title_fullStr 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title_full_unstemmed 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title_short 1-(4-Nitro­phen­yl)-1H-imidazol-3-ium chloride
title_sort 1-(4-nitro­phen­yl)-1h-imidazol-3-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588291/
https://www.ncbi.nlm.nih.gov/pubmed/23476377
http://dx.doi.org/10.1107/S1600536812050878
work_keys_str_mv AT ibrahimhalliru 14nitrophenyl1himidazol3iumchloride
AT balamuhammadd 14nitrophenyl1himidazol3iumchloride

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