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N,N-Diethyl­anilinium 5-(2,4-dinitro­phen­yl)-2,6-dioxo-1,2,3,6-tetra­hydro­pyrimidin-4-olate

The asymmetric unit of the title mol­ecular salt, C(10)H(16)N(+)·C(10)H(5)N(4)O(7) (−) (trivial name: N,N-diethyl­anilinium 2,4-dinitro­phenyl­barbiturate), comprises two anion–cation units. In the anions, the dinitro­phenyl ring and the mean plane of the barbiturate ring [planar to within 0.011 (2)...

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Detalles Bibliográficos
Autores principales: Kalaivani, Doraisamyraja, Mangaiyarkarasi, Govindan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588294/
https://www.ncbi.nlm.nih.gov/pubmed/23476417
http://dx.doi.org/10.1107/S160053681204874X
Descripción
Sumario:The asymmetric unit of the title mol­ecular salt, C(10)H(16)N(+)·C(10)H(5)N(4)O(7) (−) (trivial name: N,N-diethyl­anilinium 2,4-dinitro­phenyl­barbiturate), comprises two anion–cation units. In the anions, the dinitro­phenyl ring and the mean plane of the barbiturate ring [planar to within 0.011 (2) and 0.023 (2) Å in the two anions] are inclined to one another by 41.47 (9) and 45.12 (9)°. In the crystal, the anions are linked via strong N—H⋯O hydrogen bonds, forming chains propagating along [10-1]. Within the chains, adjacent inversion-related anionic barbiturate entities are joined through R (2) (2)(8) ring motifs. The cations are linked to the chains via N—H⋯O hydrogen bonds. The chains are linked via a number of C—H⋯O inter­actions, forming a three-dimensional structure.