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[2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3) N,C (1),N′]bromidopalladium(II)
In the title compound, [PdBr(C(17)H(17)N(2)O(5))], the Pd(II) atom is coordinated by an N,C (1),N′-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, molecules are connected by C—H⋯Br and C—H⋯O hydrogen bonds, and π–π interactions between the oxazole and...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588296/ https://www.ncbi.nlm.nih.gov/pubmed/23476330 http://dx.doi.org/10.1107/S1600536812049197 |
| _version_ | 1782261533294723072 |
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| author | Nan, Wen-Hui Tan, Jian-Ping Luo, Qun-Li |
| author_facet | Nan, Wen-Hui Tan, Jian-Ping Luo, Qun-Li |
| author_sort | Nan, Wen-Hui |
| collection | PubMed |
| description | In the title compound, [PdBr(C(17)H(17)N(2)O(5))], the Pd(II) atom is coordinated by an N,C (1),N′-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, molecules are connected by C—H⋯Br and C—H⋯O hydrogen bonds, and π–π interactions between the oxazole and benzene rings [centroid–centroid distance = 3.7344 (19) Å], resulting in a three-dimensional supramolecular structure. |
| format | Online Article Text |
| id | pubmed-3588296 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35882962013-03-08 [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3) N,C (1),N′]bromidopalladium(II) Nan, Wen-Hui Tan, Jian-Ping Luo, Qun-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(C(17)H(17)N(2)O(5))], the Pd(II) atom is coordinated by an N,C (1),N′-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, molecules are connected by C—H⋯Br and C—H⋯O hydrogen bonds, and π–π interactions between the oxazole and benzene rings [centroid–centroid distance = 3.7344 (19) Å], resulting in a three-dimensional supramolecular structure. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588296/ /pubmed/23476330 http://dx.doi.org/10.1107/S1600536812049197 Text en © Nan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Nan, Wen-Hui Tan, Jian-Ping Luo, Qun-Li [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3) N,C (1),N′]bromidopalladium(II) |
| title | [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
N,C
(1),N′]bromidopalladium(II) |
| title_full | [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
N,C
(1),N′]bromidopalladium(II) |
| title_fullStr | [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
N,C
(1),N′]bromidopalladium(II) |
| title_full_unstemmed | [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
N,C
(1),N′]bromidopalladium(II) |
| title_short | [2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
N,C
(1),N′]bromidopalladium(II) |
| title_sort | [2,6-bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ(3)
n,c
(1),n′]bromidopalladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588296/ https://www.ncbi.nlm.nih.gov/pubmed/23476330 http://dx.doi.org/10.1107/S1600536812049197 |
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