Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride

In the title compound, (C(10)H(10)N(2)S)(2)[NiCl(4)]Cl(2), the Ni(2+) cation is tetra­hedrally coordinated by four chloride anions. Two 4,4′-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N—H⋯Cl hydrogen-bonding inter­actions into 20-membered rings, in the...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588299/
https://www.ncbi.nlm.nih.gov/pubmed/23476352
http://dx.doi.org/10.1107/S1600536812050623
Descripción
Sumario:In the title compound, (C(10)H(10)N(2)S)(2)[NiCl(4)]Cl(2), the Ni(2+) cation is tetra­hedrally coordinated by four chloride anions. Two 4,4′-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N—H⋯Cl hydrogen-bonding inter­actions into 20-membered rings, in the middle of which are situated the [NiCl(4)](2−) complex anions. These rings are stacked in the b-axis direction. The Ni(2+) cation is located on a twofold rotation axis, whereas the chloride anions and the 4,4′-sulfanediyldipyridinium cations occupy general positions.

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