Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride

In the title compound, (C(10)H(10)N(2)S)(2)[NiCl(4)]Cl(2), the Ni(2+) cation is tetra­hedrally coordinated by four chloride anions. Two 4,4′-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N—H⋯Cl hydrogen-bonding inter­actions into 20-membered rings, in the...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588299/
https://www.ncbi.nlm.nih.gov/pubmed/23476352
http://dx.doi.org/10.1107/S1600536812050623
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author Werner, Julia
Jess, Inke
Näther, Christian
author_facet Werner, Julia
Jess, Inke
Näther, Christian
author_sort Werner, Julia
collection PubMed
description In the title compound, (C(10)H(10)N(2)S)(2)[NiCl(4)]Cl(2), the Ni(2+) cation is tetra­hedrally coordinated by four chloride anions. Two 4,4′-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N—H⋯Cl hydrogen-bonding inter­actions into 20-membered rings, in the middle of which are situated the [NiCl(4)](2−) complex anions. These rings are stacked in the b-axis direction. The Ni(2+) cation is located on a twofold rotation axis, whereas the chloride anions and the 4,4′-sulfanediyldipyridinium cations occupy general positions.
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spelling pubmed-35882992013-03-08 Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(10)N(2)S)(2)[NiCl(4)]Cl(2), the Ni(2+) cation is tetra­hedrally coordinated by four chloride anions. Two 4,4′-sulfanediyldipyridinium cations and two non-coordinating chloride anions are connected via N—H⋯Cl hydrogen-bonding inter­actions into 20-membered rings, in the middle of which are situated the [NiCl(4)](2−) complex anions. These rings are stacked in the b-axis direction. The Ni(2+) cation is located on a twofold rotation axis, whereas the chloride anions and the 4,4′-sulfanediyldipyridinium cations occupy general positions. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588299/ /pubmed/23476352 http://dx.doi.org/10.1107/S1600536812050623 Text en © Werner et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Werner, Julia
Jess, Inke
Näther, Christian
Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title_full Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title_fullStr Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title_full_unstemmed Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title_short Bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(II) dichloride
title_sort bis(4,4′-sulfanediyldipyridinium) tetra­chloridonickelate(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588299/
https://www.ncbi.nlm.nih.gov/pubmed/23476352
http://dx.doi.org/10.1107/S1600536812050623
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