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3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid

Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydro­thermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)meth­oxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squar...

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Detalles Bibliográficos
Autores principales: Lin, Hong, Zhang, Yi-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588300/
https://www.ncbi.nlm.nih.gov/pubmed/23476458
http://dx.doi.org/10.1107/S1600536812049550
Descripción
Sumario:Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydro­thermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)meth­oxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squares plane of 0.194 (2) Å. This plane is inclined by 35.82 (6)° to that defined by the second (pyridin-4-yl)meth­oxy group [in which the largest deviation from the least-squares plane is 0.013 (2) Å]. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds involving the acid hy­droxy group and a pyridine N atom into chains parallel to [-201].