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3,5-Bis[(pyridin-4-yl)methoxy]benzoic acid
Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydrothermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)methoxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squar...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588300/ https://www.ncbi.nlm.nih.gov/pubmed/23476458 http://dx.doi.org/10.1107/S1600536812049550 |
Sumario: | Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydrothermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)methoxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squares plane of 0.194 (2) Å. This plane is inclined by 35.82 (6)° to that defined by the second (pyridin-4-yl)methoxy group [in which the largest deviation from the least-squares plane is 0.013 (2) Å]. In the crystal, molecules are linked by O—H⋯N hydrogen bonds involving the acid hydroxy group and a pyridine N atom into chains parallel to [-201]. |
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