3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid

Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydro­thermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)meth­oxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squar...

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Detalles Bibliográficos
Autores principales: Lin, Hong, Zhang, Yi-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588300/
https://www.ncbi.nlm.nih.gov/pubmed/23476458
http://dx.doi.org/10.1107/S1600536812049550
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author Lin, Hong
Zhang, Yi-Ping
author_facet Lin, Hong
Zhang, Yi-Ping
author_sort Lin, Hong
collection PubMed
description Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydro­thermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)meth­oxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squares plane of 0.194 (2) Å. This plane is inclined by 35.82 (6)° to that defined by the second (pyridin-4-yl)meth­oxy group [in which the largest deviation from the least-squares plane is 0.013 (2) Å]. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds involving the acid hy­droxy group and a pyridine N atom into chains parallel to [-201].
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spelling pubmed-35883002013-03-08 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid Lin, Hong Zhang, Yi-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers Single crystals of the title compound, C(19)H(16)N(2)O(4), were obtained under hydro­thermal conditions by an unintended recrystallization of the employed microcrystalline starting material. The [(pyridin-4-yl)meth­oxy]benzoic acid unit is nearly planar, with a maximum deviation from the least-squares plane of 0.194 (2) Å. This plane is inclined by 35.82 (6)° to that defined by the second (pyridin-4-yl)meth­oxy group [in which the largest deviation from the least-squares plane is 0.013 (2) Å]. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds involving the acid hy­droxy group and a pyridine N atom into chains parallel to [-201]. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588300/ /pubmed/23476458 http://dx.doi.org/10.1107/S1600536812049550 Text en © Lin and Zhang 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lin, Hong
Zhang, Yi-Ping
3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title_full 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title_fullStr 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title_full_unstemmed 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title_short 3,5-Bis[(pyridin-4-yl)meth­oxy]benzoic acid
title_sort 3,5-bis[(pyridin-4-yl)meth­oxy]benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588300/
https://www.ncbi.nlm.nih.gov/pubmed/23476458
http://dx.doi.org/10.1107/S1600536812049550
work_keys_str_mv AT linhong 35bispyridin4ylmethoxybenzoicacid
AT zhangyiping 35bispyridin4ylmethoxybenzoicacid

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