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(2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate

In the title solvate, C(44)H(30)Cl(2)N(2)O(2)·2C(4)H(8)O(2), the complete polycyclic mol­ecule is generated by inversion symmetry. The dihedral angle between the quinolyl ring system (Q; r.m.s. deviation = 0.020 Å) and the pendant phenyl ring is 78.80 (6)°; the dihedral angle between Q and the centr...

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Detalles Bibliográficos
Autores principales: Kedjadja, Allaoua, Merdes, Rachid, Bouacida, Sofiane, Roisnel, Thierry, Belfaitah, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588301/
https://www.ncbi.nlm.nih.gov/pubmed/23476424
http://dx.doi.org/10.1107/S1600536812049422
Descripción
Sumario:In the title solvate, C(44)H(30)Cl(2)N(2)O(2)·2C(4)H(8)O(2), the complete polycyclic mol­ecule is generated by inversion symmetry. The dihedral angle between the quinolyl ring system (Q; r.m.s. deviation = 0.020 Å) and the pendant phenyl ring is 78.80 (6)°; the dihedral angle between Q and the central benzene ring is 85.92 (7)°. In the crystal, the components are linked by C—H⋯O and C—H⋯π inter­actions, generating (110) layers. Weak aromatic π–π stacking [centroid–centroid distances = 3.7025 (11) and 3.8124 (10) Å] is also observed.