(2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate

In the title solvate, C(44)H(30)Cl(2)N(2)O(2)·2C(4)H(8)O(2), the complete polycyclic mol­ecule is generated by inversion symmetry. The dihedral angle between the quinolyl ring system (Q; r.m.s. deviation = 0.020 Å) and the pendant phenyl ring is 78.80 (6)°; the dihedral angle between Q and the centr...

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Autores principales: Kedjadja, Allaoua, Merdes, Rachid, Bouacida, Sofiane, Roisnel, Thierry, Belfaitah, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588301/
https://www.ncbi.nlm.nih.gov/pubmed/23476424
http://dx.doi.org/10.1107/S1600536812049422
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author Kedjadja, Allaoua
Merdes, Rachid
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
author_facet Kedjadja, Allaoua
Merdes, Rachid
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
author_sort Kedjadja, Allaoua
collection PubMed
description In the title solvate, C(44)H(30)Cl(2)N(2)O(2)·2C(4)H(8)O(2), the complete polycyclic mol­ecule is generated by inversion symmetry. The dihedral angle between the quinolyl ring system (Q; r.m.s. deviation = 0.020 Å) and the pendant phenyl ring is 78.80 (6)°; the dihedral angle between Q and the central benzene ring is 85.92 (7)°. In the crystal, the components are linked by C—H⋯O and C—H⋯π inter­actions, generating (110) layers. Weak aromatic π–π stacking [centroid–centroid distances = 3.7025 (11) and 3.8124 (10) Å] is also observed.
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spelling pubmed-35883012013-03-08 (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate Kedjadja, Allaoua Merdes, Rachid Bouacida, Sofiane Roisnel, Thierry Belfaitah, Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvate, C(44)H(30)Cl(2)N(2)O(2)·2C(4)H(8)O(2), the complete polycyclic mol­ecule is generated by inversion symmetry. The dihedral angle between the quinolyl ring system (Q; r.m.s. deviation = 0.020 Å) and the pendant phenyl ring is 78.80 (6)°; the dihedral angle between Q and the central benzene ring is 85.92 (7)°. In the crystal, the components are linked by C—H⋯O and C—H⋯π inter­actions, generating (110) layers. Weak aromatic π–π stacking [centroid–centroid distances = 3.7025 (11) and 3.8124 (10) Å] is also observed. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588301/ /pubmed/23476424 http://dx.doi.org/10.1107/S1600536812049422 Text en © Kedjadja et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kedjadja, Allaoua
Merdes, Rachid
Bouacida, Sofiane
Roisnel, Thierry
Belfaitah, Ali
(2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title_full (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title_fullStr (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title_full_unstemmed (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title_short (2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
title_sort (2e,2′e)-1,1′-bis(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3,3′-(1,4-phenyl­ene)diprop-2-en-1-one ethyl acetate disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588301/
https://www.ncbi.nlm.nih.gov/pubmed/23476424
http://dx.doi.org/10.1107/S1600536812049422
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