2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene

The title compound, [Ge(4)(CH(3))(8)(C(4)H(2)S)(4)], crystallizes with one-half mol­ecule in the asymmetric unit, the whole mol­ecule being generated by inversion symmetry. The dihedral angle between adjacent thio­phene rings is 72.84 (14)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actio...

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Detalles Bibliográficos
Autores principales: Carel, Guillaume, Mallet-Ladeira, Sonia, Rima, Ghassoub, Madec, David, Castel, Annie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588302/
https://www.ncbi.nlm.nih.gov/pubmed/23476334
http://dx.doi.org/10.1107/S1600536812049720
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author Carel, Guillaume
Mallet-Ladeira, Sonia
Rima, Ghassoub
Madec, David
Castel, Annie
author_facet Carel, Guillaume
Mallet-Ladeira, Sonia
Rima, Ghassoub
Madec, David
Castel, Annie
author_sort Carel, Guillaume
collection PubMed
description The title compound, [Ge(4)(CH(3))(8)(C(4)H(2)S)(4)], crystallizes with one-half mol­ecule in the asymmetric unit, the whole mol­ecule being generated by inversion symmetry. The dihedral angle between adjacent thio­phene rings is 72.84 (14)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, leading to the formation of chains along [100].
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spelling pubmed-35883022013-03-08 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene Carel, Guillaume Mallet-Ladeira, Sonia Rima, Ghassoub Madec, David Castel, Annie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ge(4)(CH(3))(8)(C(4)H(2)S)(4)], crystallizes with one-half mol­ecule in the asymmetric unit, the whole mol­ecule being generated by inversion symmetry. The dihedral angle between adjacent thio­phene rings is 72.84 (14)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, leading to the formation of chains along [100]. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588302/ /pubmed/23476334 http://dx.doi.org/10.1107/S1600536812049720 Text en © Carel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Carel, Guillaume
Mallet-Ladeira, Sonia
Rima, Ghassoub
Madec, David
Castel, Annie
2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title_full 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title_fullStr 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title_full_unstemmed 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title_short 2,2,7,7,12,12,17,17-Octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
title_sort 2,2,7,7,12,12,17,17-octa­methyl-21,22,23,24-tetra­thia-2,7,12,17-tetra­germapenta­cyclo­[16.2.1.1(3,6).1(8,11).1(13,16)]tetra­cosa-3,5,8,10,13,15,18,20-octa­ene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588302/
https://www.ncbi.nlm.nih.gov/pubmed/23476334
http://dx.doi.org/10.1107/S1600536812049720
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