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2-Amino-5-methylpyridinium 4-methylbenzoate
The 4-methylbenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(8)H(7)O(2) (−), is nearly planar, with a dihedral angle of 6.26 (10)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyla...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588314/ https://www.ncbi.nlm.nih.gov/pubmed/23476474 http://dx.doi.org/10.1107/S1600536812050374 |
Sumario: | The 4-methylbenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(8)H(7)O(2) (−), is nearly planar, with a dihedral angle of 6.26 (10)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif, forming an approximately planar ion pair with a dihedral angle of 9.63 (4)° between the pyridinium and benzene rings. The ion pairs are further connected via N—H⋯O and weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. |
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