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2-Amino-5-methyl­pyridinium 4-methyl­benzoate

The 4-methyl­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(8)H(7)O(2) (−), is nearly planar, with a dihedral angle of 6.26 (10)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­a...

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Detalles Bibliográficos
Autores principales: Thanigaimani, Kaliyaperumal, Farhadikoutenaei, Abbas, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588314/
https://www.ncbi.nlm.nih.gov/pubmed/23476474
http://dx.doi.org/10.1107/S1600536812050374
Descripción
Sumario:The 4-methyl­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(8)H(7)O(2) (−), is nearly planar, with a dihedral angle of 6.26 (10)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif, forming an approximately planar ion pair with a dihedral angle of 9.63 (4)° between the pyridinium and benzene rings. The ion pairs are further connected via N—H⋯O and weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.