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2-Amino-5-methylpyridinium 4-chlorobenzoate
The 4-chlorobenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), is nearly planar with a dihedral angle of 5.14 (16)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588320/ https://www.ncbi.nlm.nih.gov/pubmed/23476392 http://dx.doi.org/10.1107/S1600536812051021 |
Sumario: | The 4-chlorobenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), is nearly planar with a dihedral angle of 5.14 (16)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O and weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. The crystal structure also features a π–π stacking interaction between the pyridinium and benzene rings with a centroid–centroid distance of 3.7948 (9) Å. |
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