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2-Amino-5-methyl­pyridinium 4-chloro­benzoate

The 4-chloro­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), is nearly planar with a dihedral angle of 5.14 (16)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­...

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Detalles Bibliográficos
Autores principales: Thanigaimani, Kaliyaperumal, Farhadikoutenaei, Abbas, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588320/
https://www.ncbi.nlm.nih.gov/pubmed/23476392
http://dx.doi.org/10.1107/S1600536812051021
Descripción
Sumario:The 4-chloro­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), is nearly planar with a dihedral angle of 5.14 (16)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds with an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O and weak C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. The crystal structure also features a π–π stacking inter­action between the pyridinium and benzene rings with a centroid–centroid distance of 3.7948 (9) Å.