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(η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-ylidene)bis(pentafluorobenzoato-κO)ruthenium(II) dichloromethane disolvate
The title compound, [Ru(C(7)F(5)O(2))(2)(C(10)H(14))(C(21)H(24)N(2))]·2CH(2)Cl(2), is formed as an orange crystalline powder by the reaction of RuCl(2)(p-cymene)(IMes) and AgOCOC(6)F(5) in anhydrous tetrahydrofuran (IMes = 1,3-dimesityl-2,3-dihydro-1H-imidazol-2-ylidene). The asymetric unit cons...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588321/ https://www.ncbi.nlm.nih.gov/pubmed/23476327 http://dx.doi.org/10.1107/S1600536812049513 |
| Sumario: | The title compound, [Ru(C(7)F(5)O(2))(2)(C(10)H(14))(C(21)H(24)N(2))]·2CH(2)Cl(2), is formed as an orange crystalline powder by the reaction of RuCl(2)(p-cymene)(IMes) and AgOCOC(6)F(5) in anhydrous tetrahydrofuran (IMes = 1,3-dimesityl-2,3-dihydro-1H-imidazol-2-ylidene). The asymetric unit consists of two independent [Ru(C(6)F(5)COO)(2)(η(6)-p-cymene)(IMes)] complexes and four dichloromethane solvent molecules. In each complex molecule, the Ru atom presents a pseudo-octahedral environment with the p-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the pentafluorobenzoate ligands and by the imidazolylidene ligand. |
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