(η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate

The title compound, [Ru(C(7)F(5)O(2))(2)(C(10)H(14))(C(21)H(24)N(2))]·2CH(2)Cl(2), is formed as an orange crystalline powder by the reaction of RuCl(2)(p-cymene)(IMes) and AgOCOC(6)F(5) in anhydrous tetra­hydro­furan (IMes = 1,3-dimesityl-2,3-di­hydro-1H-imidazol-2-yl­idene). The asymetric unit cons...

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Autores principales: Dorst, Konstantin, Frey, Wolfgang, Wang, Dongren, Buchmeiser, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588321/
https://www.ncbi.nlm.nih.gov/pubmed/23476327
http://dx.doi.org/10.1107/S1600536812049513
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author Dorst, Konstantin
Frey, Wolfgang
Wang, Dongren
Buchmeiser, Michael
author_facet Dorst, Konstantin
Frey, Wolfgang
Wang, Dongren
Buchmeiser, Michael
author_sort Dorst, Konstantin
collection PubMed
description The title compound, [Ru(C(7)F(5)O(2))(2)(C(10)H(14))(C(21)H(24)N(2))]·2CH(2)Cl(2), is formed as an orange crystalline powder by the reaction of RuCl(2)(p-cymene)(IMes) and AgOCOC(6)F(5) in anhydrous tetra­hydro­furan (IMes = 1,3-dimesityl-2,3-di­hydro-1H-imidazol-2-yl­idene). The asymetric unit consists of two independent [Ru(C(6)F(5)COO)(2)(η(6)-p-cymene)(IMes)] com­plexes and four dichloro­methane solvent mol­ecules. In each complex molecule, the Ru atom presents a pseudo-octa­hedral environment with the p-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the penta­fluoro­benzoate ligands and by the imidazolyl­idene ligand.
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spelling pubmed-35883212013-03-08 (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate Dorst, Konstantin Frey, Wolfgang Wang, Dongren Buchmeiser, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(7)F(5)O(2))(2)(C(10)H(14))(C(21)H(24)N(2))]·2CH(2)Cl(2), is formed as an orange crystalline powder by the reaction of RuCl(2)(p-cymene)(IMes) and AgOCOC(6)F(5) in anhydrous tetra­hydro­furan (IMes = 1,3-dimesityl-2,3-di­hydro-1H-imidazol-2-yl­idene). The asymetric unit consists of two independent [Ru(C(6)F(5)COO)(2)(η(6)-p-cymene)(IMes)] com­plexes and four dichloro­methane solvent mol­ecules. In each complex molecule, the Ru atom presents a pseudo-octa­hedral environment with the p-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the penta­fluoro­benzoate ligands and by the imidazolyl­idene ligand. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588321/ /pubmed/23476327 http://dx.doi.org/10.1107/S1600536812049513 Text en © Dorst et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dorst, Konstantin
Frey, Wolfgang
Wang, Dongren
Buchmeiser, Michael
(η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title_full (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title_fullStr (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title_full_unstemmed (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title_short (η(6)-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κO)ruthenium(II) dichloro­methane disolvate
title_sort (η(6)-p-cymene)(1,3-dimesityl-2,3-dihydro-1h-imidazol-2-yl­idene)bis­(pentafluorobenzoato-κo)ruthenium(ii) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588321/
https://www.ncbi.nlm.nih.gov/pubmed/23476327
http://dx.doi.org/10.1107/S1600536812049513
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AT wangdongren ē6pcymene13dimesityl23dihydro1himidazol2ylidenebispentafluorobenzoatokorutheniumiidichloromethanedisolvate
AT buchmeisermichael ē6pcymene13dimesityl23dihydro1himidazol2ylidenebispentafluorobenzoatokorutheniumiidichloromethanedisolvate

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