Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]

In the title compound, [Li(2)(C(6)H(3)N(2)O(4))(2)(NO(3))](n), the two symmetry-independent Li(I) ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each Li(I) ion is also coordinated by two O atoms from nitra...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588327/
https://www.ncbi.nlm.nih.gov/pubmed/23476354
http://dx.doi.org/10.1107/S1600536812050738
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description In the title compound, [Li(2)(C(6)H(3)N(2)O(4))(2)(NO(3))](n), the two symmetry-independent Li(I) ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each Li(I) ion is also coordinated by two O atoms from nitrate ions, connecting the ribbons into a three-dimensional network. Very strong intra­molecular O—H⋯O hydrogen bonds occur between the carboxyl and the carboxylate group.
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spelling pubmed-35883272013-03-08 Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(2)(C(6)H(3)N(2)O(4))(2)(NO(3))](n), the two symmetry-independent Li(I) ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each Li(I) ion is also coordinated by two O atoms from nitrate ions, connecting the ribbons into a three-dimensional network. Very strong intra­molecular O—H⋯O hydrogen bonds occur between the carboxyl and the carboxylate group. International Union of Crystallography 2012-12-19 /pmc/articles/PMC3588327/ /pubmed/23476354 http://dx.doi.org/10.1107/S1600536812050738 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title_full Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title_fullStr Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title_full_unstemmed Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title_short Poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
title_sort poly[(μ(4)-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ(4)-nitrato)dilithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588327/
https://www.ncbi.nlm.nih.gov/pubmed/23476354
http://dx.doi.org/10.1107/S1600536812050738
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