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[μ-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)]
The binuclear title compound, [Cu(2)(C(12)H(10)N(6)S(2))Cl(2)], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N (1),N (2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbo...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588330/ https://www.ncbi.nlm.nih.gov/pubmed/23476341 http://dx.doi.org/10.1107/S1600536812048659 |
Sumario: | The binuclear title compound, [Cu(2)(C(12)H(10)N(6)S(2))Cl(2)], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N (1),N (2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidate ligand, and one Cl(−) anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The molecule is bow-shaped with the pyridine rings inclined to one another by 51.56 (14)°. In the crystal, N—H⋯Cl hydrogen bonds lead to the formation of ribbons propagating along [001]. These ribbons are connected via C—H⋯Cl, C—H⋯S and π–π interactions [centroid–centroid distance = 3.6146 (19) Å], leading to the formation of a three-dimensional structure. |
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