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[μ-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)]
The binuclear title compound, [Cu(2)(C(12)H(10)N(6)S(2))Cl(2)], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N (1),N (2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbo...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588330/ https://www.ncbi.nlm.nih.gov/pubmed/23476341 http://dx.doi.org/10.1107/S1600536812048659 |
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author | Liu, Yang Zhang, Bingguang Deng, Kejian |
author_facet | Liu, Yang Zhang, Bingguang Deng, Kejian |
author_sort | Liu, Yang |
collection | PubMed |
description | The binuclear title compound, [Cu(2)(C(12)H(10)N(6)S(2))Cl(2)], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N (1),N (2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidate ligand, and one Cl(−) anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The molecule is bow-shaped with the pyridine rings inclined to one another by 51.56 (14)°. In the crystal, N—H⋯Cl hydrogen bonds lead to the formation of ribbons propagating along [001]. These ribbons are connected via C—H⋯Cl, C—H⋯S and π–π interactions [centroid–centroid distance = 3.6146 (19) Å], leading to the formation of a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3588330 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883302013-03-08 [μ-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] Liu, Yang Zhang, Bingguang Deng, Kejian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title compound, [Cu(2)(C(12)H(10)N(6)S(2))Cl(2)], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N (1),N (2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidate ligand, and one Cl(−) anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The molecule is bow-shaped with the pyridine rings inclined to one another by 51.56 (14)°. In the crystal, N—H⋯Cl hydrogen bonds lead to the formation of ribbons propagating along [001]. These ribbons are connected via C—H⋯Cl, C—H⋯S and π–π interactions [centroid–centroid distance = 3.6146 (19) Å], leading to the formation of a three-dimensional structure. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588330/ /pubmed/23476341 http://dx.doi.org/10.1107/S1600536812048659 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yang Zhang, Bingguang Deng, Kejian [μ-N (1),N (2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title | [μ-N
(1),N
(2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title_full | [μ-N
(1),N
(2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title_fullStr | [μ-N
(1),N
(2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title_full_unstemmed | [μ-N
(1),N
(2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title_short | [μ-N
(1),N
(2)-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)] |
title_sort | [μ-n
(1),n
(2)-bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588330/ https://www.ncbi.nlm.nih.gov/pubmed/23476341 http://dx.doi.org/10.1107/S1600536812048659 |
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