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Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate
The molecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phenyl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitrobenzamide group are ne...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588331/ https://www.ncbi.nlm.nih.gov/pubmed/23476476 http://dx.doi.org/10.1107/S1600536812050180 |
Sumario: | The molecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phenyl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitrobenzamide group are nearly perpendicular, making a dihedral angle of 89.55 (9)°. All nitro groups lie almost in plane with the associated aromatic rings, the O—N—C—C torsion angles ranging from 9.2 (2) to 24.3 (2)°. In the crystal, strong anion–anion N—H⋯O and anion–cation hydrogen bonds form inversion dimers stacked along the a axis. Less prominent anion–anion C—H⋯O interactions lead to the formation of a three-dimensional network including anion–anion dimers as well as anion–anion chains along [100?]. |
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