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Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate
The molecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phenyl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitrobenzamide group are ne...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588331/ https://www.ncbi.nlm.nih.gov/pubmed/23476476 http://dx.doi.org/10.1107/S1600536812050180 |
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author | Waris, Ghulam Siddiqi, Humaira Masood Flörke, Ulrich Hussain, Rizwan Butt, M. Saeed |
author_facet | Waris, Ghulam Siddiqi, Humaira Masood Flörke, Ulrich Hussain, Rizwan Butt, M. Saeed |
author_sort | Waris, Ghulam |
collection | PubMed |
description | The molecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phenyl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitrobenzamide group are nearly perpendicular, making a dihedral angle of 89.55 (9)°. All nitro groups lie almost in plane with the associated aromatic rings, the O—N—C—C torsion angles ranging from 9.2 (2) to 24.3 (2)°. In the crystal, strong anion–anion N—H⋯O and anion–cation hydrogen bonds form inversion dimers stacked along the a axis. Less prominent anion–anion C—H⋯O interactions lead to the formation of a three-dimensional network including anion–anion dimers as well as anion–anion chains along [100?]. |
format | Online Article Text |
id | pubmed-3588331 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883312013-03-08 Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate Waris, Ghulam Siddiqi, Humaira Masood Flörke, Ulrich Hussain, Rizwan Butt, M. Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phenyl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitrobenzamide group are nearly perpendicular, making a dihedral angle of 89.55 (9)°. All nitro groups lie almost in plane with the associated aromatic rings, the O—N—C—C torsion angles ranging from 9.2 (2) to 24.3 (2)°. In the crystal, strong anion–anion N—H⋯O and anion–cation hydrogen bonds form inversion dimers stacked along the a axis. Less prominent anion–anion C—H⋯O interactions lead to the formation of a three-dimensional network including anion–anion dimers as well as anion–anion chains along [100?]. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588331/ /pubmed/23476476 http://dx.doi.org/10.1107/S1600536812050180 Text en © Waris et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Waris, Ghulam Siddiqi, Humaira Masood Flörke, Ulrich Hussain, Rizwan Butt, M. Saeed Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title | Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title_full | Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title_fullStr | Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title_full_unstemmed | Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title_short | Triethylammonium 4-(3,5-dinitrobenzamido)-N-(3,5-dinitrobenzoyl)benzenesulfonamidate |
title_sort | triethylammonium 4-(3,5-dinitrobenzamido)-n-(3,5-dinitrobenzoyl)benzenesulfonamidate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588331/ https://www.ncbi.nlm.nih.gov/pubmed/23476476 http://dx.doi.org/10.1107/S1600536812050180 |
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