Cargando…

Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate

The mol­ecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phen­yl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitro­benzamide group are ne...

Descripción completa

Detalles Bibliográficos
Autores principales: Waris, Ghulam, Siddiqi, Humaira Masood, Flörke, Ulrich, Hussain, Rizwan, Butt, M. Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588331/
https://www.ncbi.nlm.nih.gov/pubmed/23476476
http://dx.doi.org/10.1107/S1600536812050180
_version_ 1782261541234540544
author Waris, Ghulam
Siddiqi, Humaira Masood
Flörke, Ulrich
Hussain, Rizwan
Butt, M. Saeed
author_facet Waris, Ghulam
Siddiqi, Humaira Masood
Flörke, Ulrich
Hussain, Rizwan
Butt, M. Saeed
author_sort Waris, Ghulam
collection PubMed
description The mol­ecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phen­yl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitro­benzamide group are nearly perpendicular, making a dihedral angle of 89.55 (9)°. All nitro groups lie almost in plane with the associated aromatic rings, the O—N—C—C torsion angles ranging from 9.2 (2) to 24.3 (2)°. In the crystal, strong anion–anion N—H⋯O and anion–cation hydrogen bonds form inversion dimers stacked along the a axis. Less prominent anion–anion C—H⋯O inter­actions lead to the formation of a three-dimensional network including anion–anion dimers as well as anion–anion chains along [100?].
format Online
Article
Text
id pubmed-3588331
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35883312013-03-08 Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate Waris, Ghulam Siddiqi, Humaira Masood Flörke, Ulrich Hussain, Rizwan Butt, M. Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title salt, C(6)H(16)N(+)·C(20)H(11)N(6)O(12)S(−), shows a planar geometry of the benzamido–phen­yl–sulfonyl moiety, with a dihedral angle of 1.59 (9)° between the aromatic ring planes. The central ring and the aromatic ring of the other dinitro­benzamide group are nearly perpendicular, making a dihedral angle of 89.55 (9)°. All nitro groups lie almost in plane with the associated aromatic rings, the O—N—C—C torsion angles ranging from 9.2 (2) to 24.3 (2)°. In the crystal, strong anion–anion N—H⋯O and anion–cation hydrogen bonds form inversion dimers stacked along the a axis. Less prominent anion–anion C—H⋯O inter­actions lead to the formation of a three-dimensional network including anion–anion dimers as well as anion–anion chains along [100?]. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588331/ /pubmed/23476476 http://dx.doi.org/10.1107/S1600536812050180 Text en © Waris et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Waris, Ghulam
Siddiqi, Humaira Masood
Flörke, Ulrich
Hussain, Rizwan
Butt, M. Saeed
Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title_full Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title_fullStr Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title_full_unstemmed Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title_short Triethyl­ammonium 4-(3,5-dinitro­benzamido)-N-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
title_sort triethyl­ammonium 4-(3,5-dinitro­benzamido)-n-(3,5-dinitro­benzo­yl)benzene­sulfonamidate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588331/
https://www.ncbi.nlm.nih.gov/pubmed/23476476
http://dx.doi.org/10.1107/S1600536812050180
work_keys_str_mv AT warisghulam triethylammonium435dinitrobenzamidon35dinitrobenzoylbenzenesulfonamidate
AT siddiqihumairamasood triethylammonium435dinitrobenzamidon35dinitrobenzoylbenzenesulfonamidate
AT florkeulrich triethylammonium435dinitrobenzamidon35dinitrobenzoylbenzenesulfonamidate
AT hussainrizwan triethylammonium435dinitrobenzamidon35dinitrobenzoylbenzenesulfonamidate
AT buttmsaeed triethylammonium435dinitrobenzamidon35dinitrobenzoylbenzenesulfonamidate