(E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide

In the title compound, C(14)H(12)ClN(3)O(2), the acyl­hydrazone base [C(=O)—N—N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion d...

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Detalles Bibliográficos
Autores principales: Rao, Xiao-jin, Wu, Wen-Shi, Li, Chuan-hui, Huang, Yu-min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588333/
https://www.ncbi.nlm.nih.gov/pubmed/23476415
http://dx.doi.org/10.1107/S1600536812045989
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author Rao, Xiao-jin
Wu, Wen-Shi
Li, Chuan-hui
Huang, Yu-min
author_facet Rao, Xiao-jin
Wu, Wen-Shi
Li, Chuan-hui
Huang, Yu-min
author_sort Rao, Xiao-jin
collection PubMed
description In the title compound, C(14)H(12)ClN(3)O(2), the acyl­hydrazone base [C(=O)—N—N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) graph-set motif. The dimers are linked via C—H⋯π interactions forming chains along [101].
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spelling pubmed-35883332013-03-08 (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide Rao, Xiao-jin Wu, Wen-Shi Li, Chuan-hui Huang, Yu-min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)ClN(3)O(2), the acyl­hydrazone base [C(=O)—N—N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(8) graph-set motif. The dimers are linked via C—H⋯π interactions forming chains along [101]. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588333/ /pubmed/23476415 http://dx.doi.org/10.1107/S1600536812045989 Text en © Rao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rao, Xiao-jin
Wu, Wen-Shi
Li, Chuan-hui
Huang, Yu-min
(E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title_full (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title_fullStr (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title_full_unstemmed (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title_short (E)-2-(4-Chloro­phen­oxy)-N′-(pyridin-4-yl­methyl­idene)acetohydrazide
title_sort (e)-2-(4-chloro­phen­oxy)-n′-(pyridin-4-yl­methyl­idene)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588333/
https://www.ncbi.nlm.nih.gov/pubmed/23476415
http://dx.doi.org/10.1107/S1600536812045989
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