Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) hemihydrate

In the title hydrated mol­ecular salt, [Fe(C(12)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·0.5H(2)O, the water mol­ecule site is half-occupied. The Fe—N bond lengths within the octa­hedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d (6) electronic configuration...

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Detalles Bibliográficos
Autores principales: Setifi, Zouaoui, Setifi, Fatima, Ng, Seik Weng, Oudahmane, Abdelghani, El-Ghozzi, Malika, Avignant, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588335/
https://www.ncbi.nlm.nih.gov/pubmed/23476315
http://dx.doi.org/10.1107/S1600536812048611
Descripción
Sumario:In the title hydrated mol­ecular salt, [Fe(C(12)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·0.5H(2)O, the water mol­ecule site is half-occupied. The Fe—N bond lengths within the octa­hedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d (6) electronic configuration for the metal ion. The C—N, C—C and C—O bond lengths in the polynitrile anions indicate extensive electronic delocalization. In the crystal, the components are linked through O—H⋯N hydrogen bonds, forming [100] chains, as well as through Coulombic inter­actions.

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