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Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate
In the title hydrated molecular salt, [Fe(C(12)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·0.5H(2)O, the water molecule site is half-occupied. The Fe—N bond lengths within the octahedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d (6) electronic configuration...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588335/ https://www.ncbi.nlm.nih.gov/pubmed/23476315 http://dx.doi.org/10.1107/S1600536812048611 |
| _version_ | 1782261542136315904 |
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| author | Setifi, Zouaoui Setifi, Fatima Ng, Seik Weng Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel |
| author_facet | Setifi, Zouaoui Setifi, Fatima Ng, Seik Weng Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel |
| author_sort | Setifi, Zouaoui |
| collection | PubMed |
| description | In the title hydrated molecular salt, [Fe(C(12)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·0.5H(2)O, the water molecule site is half-occupied. The Fe—N bond lengths within the octahedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d (6) electronic configuration for the metal ion. The C—N, C—C and C—O bond lengths in the polynitrile anions indicate extensive electronic delocalization. In the crystal, the components are linked through O—H⋯N hydrogen bonds, forming [100] chains, as well as through Coulombic interactions. |
| format | Online Article Text |
| id | pubmed-3588335 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35883352013-03-08 Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate Setifi, Zouaoui Setifi, Fatima Ng, Seik Weng Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated molecular salt, [Fe(C(12)H(8)N(2))(3)](C(9)H(5)N(4)O)(2)·0.5H(2)O, the water molecule site is half-occupied. The Fe—N bond lengths within the octahedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d (6) electronic configuration for the metal ion. The C—N, C—C and C—O bond lengths in the polynitrile anions indicate extensive electronic delocalization. In the crystal, the components are linked through O—H⋯N hydrogen bonds, forming [100] chains, as well as through Coulombic interactions. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588335/ /pubmed/23476315 http://dx.doi.org/10.1107/S1600536812048611 Text en © Setifi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Setifi, Zouaoui Setifi, Fatima Ng, Seik Weng Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel Tris(1,10-phenanthroline-κ(2) N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title_full | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title_fullStr | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title_full_unstemmed | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title_short | Tris(1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| title_sort | tris(1,10-phenanthroline-κ(2)
n,n′)iron(ii) bis(1,1,3,3-tetracyano-2-ethoxypropenide) hemihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588335/ https://www.ncbi.nlm.nih.gov/pubmed/23476315 http://dx.doi.org/10.1107/S1600536812048611 |
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