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(Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2) C (1),N)palladium(II)
In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588341/ https://www.ncbi.nlm.nih.gov/pubmed/23476333 http://dx.doi.org/10.1107/S1600536812049768 |
Sumario: | In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π interaction. In the crystal, molecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction. |
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