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(Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)

In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well...

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Autores principales: Mafud, Ana C., Oliviera, Milene A. R., Gambardella, Maria T. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588341/
https://www.ncbi.nlm.nih.gov/pubmed/23476333
http://dx.doi.org/10.1107/S1600536812049768
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author Mafud, Ana C.
Oliviera, Milene A. R.
Gambardella, Maria T. P.
author_facet Mafud, Ana C.
Oliviera, Milene A. R.
Gambardella, Maria T. P.
author_sort Mafud, Ana C.
collection PubMed
description In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π inter­action. In the crystal, mol­ecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction.
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spelling pubmed-35883412013-03-08 (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II) Mafud, Ana C. Oliviera, Milene A. R. Gambardella, Maria T. P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π inter­action. In the crystal, mol­ecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588341/ /pubmed/23476333 http://dx.doi.org/10.1107/S1600536812049768 Text en © Mafud et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mafud, Ana C.
Oliviera, Milene A. R.
Gambardella, Maria T. P.
(Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title_full (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title_fullStr (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title_full_unstemmed (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title_short (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)
title_sort (benzyl isocyanide-κc (1))chlorido(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) c (1),n)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588341/
https://www.ncbi.nlm.nih.gov/pubmed/23476333
http://dx.doi.org/10.1107/S1600536812049768
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