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(Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2) C (1),N)palladium(II)
In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588341/ https://www.ncbi.nlm.nih.gov/pubmed/23476333 http://dx.doi.org/10.1107/S1600536812049768 |
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author | Mafud, Ana C. Oliviera, Milene A. R. Gambardella, Maria T. P. |
author_facet | Mafud, Ana C. Oliviera, Milene A. R. Gambardella, Maria T. P. |
author_sort | Mafud, Ana C. |
collection | PubMed |
description | In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π interaction. In the crystal, molecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction. |
format | Online Article Text |
id | pubmed-3588341 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883412013-03-08 (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2) C (1),N)palladium(II) Mafud, Ana C. Oliviera, Milene A. R. Gambardella, Maria T. P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(11)H(13)ClN)Cl(C(8)H(7)N)], which crystallized in the chiral space group P2(1)2(1)2(1), the Pd(II) atom is coordinated by two C atoms, a Csp (2) atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H⋯Cl hydrogen bond and a C—H⋯π interaction. In the crystal, molecules are linked via C—H⋯Cl hydrogen bonds, forming chains along the a-axis direction. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588341/ /pubmed/23476333 http://dx.doi.org/10.1107/S1600536812049768 Text en © Mafud et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mafud, Ana C. Oliviera, Milene A. R. Gambardella, Maria T. P. (Benzyl isocyanide-κC (1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2) C (1),N)palladium(II) |
title | (Benzyl isocyanide-κC
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
C
(1),N)palladium(II) |
title_full | (Benzyl isocyanide-κC
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
C
(1),N)palladium(II) |
title_fullStr | (Benzyl isocyanide-κC
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
C
(1),N)palladium(II) |
title_full_unstemmed | (Benzyl isocyanide-κC
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
C
(1),N)palladium(II) |
title_short | (Benzyl isocyanide-κC
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
C
(1),N)palladium(II) |
title_sort | (benzyl isocyanide-κc
(1))chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2)
c
(1),n)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588341/ https://www.ncbi.nlm.nih.gov/pubmed/23476333 http://dx.doi.org/10.1107/S1600536812049768 |
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