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Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2) N (1),N (5))nickel(II) methanol monosolvate
The title compound, [Ni(C(4)H(8)N(3))(2)]·CH(3)OH, contains two independent Ni(II) atoms, each located on an inversion center and coordinated by four N atoms from two 1-[(1-iminoethyl)imino]ethyl}azanide ligands in a square-planar geometry. N—H⋯N, N—H⋯O and O—H⋯N hydrogen bonds link the complex...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588343/ https://www.ncbi.nlm.nih.gov/pubmed/23476329 http://dx.doi.org/10.1107/S1600536812046958 |
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author | Xie, Yong-Qiang Li, Jun-Jian Guo, Ying Zhang, You-Ming Wei, Tai-Bao |
author_facet | Xie, Yong-Qiang Li, Jun-Jian Guo, Ying Zhang, You-Ming Wei, Tai-Bao |
author_sort | Xie, Yong-Qiang |
collection | PubMed |
description | The title compound, [Ni(C(4)H(8)N(3))(2)]·CH(3)OH, contains two independent Ni(II) atoms, each located on an inversion center and coordinated by four N atoms from two 1-[(1-iminoethyl)imino]ethyl}azanide ligands in a square-planar geometry. N—H⋯N, N—H⋯O and O—H⋯N hydrogen bonds link the complex molecules and methanol solvent molecules into a corrugated layer parallel to (001). |
format | Online Article Text |
id | pubmed-3588343 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883432013-03-08 Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2) N (1),N (5))nickel(II) methanol monosolvate Xie, Yong-Qiang Li, Jun-Jian Guo, Ying Zhang, You-Ming Wei, Tai-Bao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(4)H(8)N(3))(2)]·CH(3)OH, contains two independent Ni(II) atoms, each located on an inversion center and coordinated by four N atoms from two 1-[(1-iminoethyl)imino]ethyl}azanide ligands in a square-planar geometry. N—H⋯N, N—H⋯O and O—H⋯N hydrogen bonds link the complex molecules and methanol solvent molecules into a corrugated layer parallel to (001). International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588343/ /pubmed/23476329 http://dx.doi.org/10.1107/S1600536812046958 Text en © Xie et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xie, Yong-Qiang Li, Jun-Jian Guo, Ying Zhang, You-Ming Wei, Tai-Bao Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2) N (1),N (5))nickel(II) methanol monosolvate |
title | Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
N
(1),N
(5))nickel(II) methanol monosolvate |
title_full | Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
N
(1),N
(5))nickel(II) methanol monosolvate |
title_fullStr | Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
N
(1),N
(5))nickel(II) methanol monosolvate |
title_full_unstemmed | Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
N
(1),N
(5))nickel(II) methanol monosolvate |
title_short | Bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
N
(1),N
(5))nickel(II) methanol monosolvate |
title_sort | bis({1-[(1-iminoethyl)imino]ethyl}azanido-κ(2)
n
(1),n
(5))nickel(ii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588343/ https://www.ncbi.nlm.nih.gov/pubmed/23476329 http://dx.doi.org/10.1107/S1600536812046958 |
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