N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate

In the title salt, C(19)H(25)N(4)O(+)·C(24)H(20)B(−), the C=N and C—N bond lengths in the CN(3) unit are 1.3327 (8)/1.3364 (9) and 1.3802 (9) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 118.77 (6), 120.29 (6) and 120.81 (6)°, showing only a small deviation of...

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Autor principal: Tiritiris, Ioannis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588347/
https://www.ncbi.nlm.nih.gov/pubmed/23476477
http://dx.doi.org/10.1107/S1600536812050507
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author Tiritiris, Ioannis
author_facet Tiritiris, Ioannis
author_sort Tiritiris, Ioannis
collection PubMed
description In the title salt, C(19)H(25)N(4)O(+)·C(24)H(20)B(−), the C=N and C—N bond lengths in the CN(3) unit are 1.3327 (8)/1.3364 (9) and 1.3802 (9) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 118.77 (6), 120.29 (6) and 120.81 (6)°, showing only a small deviation of the CN(3) plane from an ideal trigonal-planar geometry. The bonds between the N atoms and the terminal methyl C atoms all have values close to a typical single bond [1.4636 (9)–1.4772 (9) Å]. The crystal packing is caused by electrostatic inter­actions between cations and anions.
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spelling pubmed-35883472013-03-08 N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(19)H(25)N(4)O(+)·C(24)H(20)B(−), the C=N and C—N bond lengths in the CN(3) unit are 1.3327 (8)/1.3364 (9) and 1.3802 (9) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 118.77 (6), 120.29 (6) and 120.81 (6)°, showing only a small deviation of the CN(3) plane from an ideal trigonal-planar geometry. The bonds between the N atoms and the terminal methyl C atoms all have values close to a typical single bond [1.4636 (9)–1.4772 (9) Å]. The crystal packing is caused by electrostatic inter­actions between cations and anions. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588347/ /pubmed/23476477 http://dx.doi.org/10.1107/S1600536812050507 Text en © Ioannis Tiritiris 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title_full N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title_fullStr N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title_full_unstemmed N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title_short N-(Diphenyl­carbamo­yl)-N,N′,N′,N′′,N′′-penta­methyl­guanidinium tetra­phenyl­borate
title_sort n-(diphenyl­carbamo­yl)-n,n′,n′,n′′,n′′-penta­methyl­guanidinium tetra­phenyl­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588347/
https://www.ncbi.nlm.nih.gov/pubmed/23476477
http://dx.doi.org/10.1107/S1600536812050507
work_keys_str_mv AT tiritirisioannis ndiphenylcarbamoylnnnnnpentamethylguanidiniumtetraphenylborate

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