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3-Hydroxy-1-(4-methoxybenzyl)piperidin-2-one
The title compound, C(13)H(17)NO(3), adopts a conformation in which the aromatic ring and the mean plane of the piperidine ring are almost perpendicular to each other [dihedral angle = 79.25 (6)°]. The presence of the carbonyl group alters the conformation of the piperidine ring from a chair to a tw...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588348/ https://www.ncbi.nlm.nih.gov/pubmed/23476435 http://dx.doi.org/10.1107/S1600536812049501 |
| Sumario: | The title compound, C(13)H(17)NO(3), adopts a conformation in which the aromatic ring and the mean plane of the piperidine ring are almost perpendicular to each other [dihedral angle = 79.25 (6)°]. The presence of the carbonyl group alters the conformation of the piperidine ring from a chair to a twisted half-chair conformation. In the crystal, pairs of strong O—H⋯O hydrogen bonds link the molecules into inversion dimers. Weak C—H⋯O interactions extend the hydrogen-bonding network into three dimensions. |
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