Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate

In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Co(II) atom (site symmetry 2) has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate ligand, in which the S atom has site sy...

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Detalles Bibliográficos
Autor principal: Zhong, Kai-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588351/
https://www.ncbi.nlm.nih.gov/pubmed/23476325
http://dx.doi.org/10.1107/S1600536812049616
Descripción
Sumario:In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Co(II) atom (site symmetry 2) has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N(2)C(2) groups is 84.46 (15)°. The complex and solvent mol­ecules are connected through O—H⋯O hydrogen bonds. The solvent mol­ecule is equally disordered over two positions and is also located on a twofold axis.

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