Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate

In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Co(II) atom (site symmetry 2) has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate ligand, in which the S atom has site sy...

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Autor principal: Zhong, Kai-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588351/
https://www.ncbi.nlm.nih.gov/pubmed/23476325
http://dx.doi.org/10.1107/S1600536812049616
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author Zhong, Kai-Long
author_facet Zhong, Kai-Long
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Co(II) atom (site symmetry 2) has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N(2)C(2) groups is 84.46 (15)°. The complex and solvent mol­ecules are connected through O—H⋯O hydrogen bonds. The solvent mol­ecule is equally disordered over two positions and is also located on a twofold axis.
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spelling pubmed-35883512013-03-08 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Co(II) atom (site symmetry 2) has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N(2)C(2) groups is 84.46 (15)°. The complex and solvent mol­ecules are connected through O—H⋯O hydrogen bonds. The solvent mol­ecule is equally disordered over two positions and is also located on a twofold axis. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588351/ /pubmed/23476325 http://dx.doi.org/10.1107/S1600536812049616 Text en © Kai-Long Zhong 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) propane-1,2-diol monosolvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)cobalt(ii) propane-1,2-diol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588351/
https://www.ncbi.nlm.nih.gov/pubmed/23476325
http://dx.doi.org/10.1107/S1600536812049616
work_keys_str_mv AT zhongkailong bis110phenanthrolinek2nnsulfatok2oocobaltiipropane12diolmonosolvate

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