2-(Adamantan-1-yl)-1,3-bis­(4-methyl­phen­yl)propan-2-ol

The conformation of the title compound, C(27)H(34)O, is stabilized by a weak intra­molecular C—H⋯π inter­action. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range...

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Detalles Bibliográficos
Autores principales: Babjaková, Eva, Bartoš, Peter, Vícha, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588353/
https://www.ncbi.nlm.nih.gov/pubmed/23476370
http://dx.doi.org/10.1107/S1600536812050647
Descripción
Sumario:The conformation of the title compound, C(27)H(34)O, is stabilized by a weak intra­molecular C—H⋯π inter­action. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 107.75 (10)–111.35 (9)°. Although the mol­ecule contains a hy­droxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed in the crystal structure.

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