Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)

In the title complex, [AuCl(C(24)H(20)NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the ‘soft’ P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au—P = 2.2321 (13) Å, Au—Cl = 2.2820 (13) Å and P...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588354/
https://www.ncbi.nlm.nih.gov/pubmed/23476348
http://dx.doi.org/10.1107/S1600536812050404
Descripción
Sumario:In the title complex, [AuCl(C(24)H(20)NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the ‘soft’ P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au—P = 2.2321 (13) Å, Au—Cl = 2.2820 (13) Å and P—Au—Cl = 176.49 (5)°. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio.

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