Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)

In the title complex, [AuCl(C(24)H(20)NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the ‘soft’ P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au—P = 2.2321 (13) Å, Au—Cl = 2.2820 (13) Å and P...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588354/
https://www.ncbi.nlm.nih.gov/pubmed/23476348
http://dx.doi.org/10.1107/S1600536812050404
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author Chiririwa, Haleden
Davis, Wade L.
author_facet Chiririwa, Haleden
Davis, Wade L.
author_sort Chiririwa, Haleden
collection PubMed
description In the title complex, [AuCl(C(24)H(20)NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the ‘soft’ P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au—P = 2.2321 (13) Å, Au—Cl = 2.2820 (13) Å and P—Au—Cl = 176.49 (5)°. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio.
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spelling pubmed-35883542013-03-08 Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I) Chiririwa, Haleden Davis, Wade L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [AuCl(C(24)H(20)NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the ‘soft’ P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au—P = 2.2321 (13) Å, Au—Cl = 2.2820 (13) Å and P—Au—Cl = 176.49 (5)°. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588354/ /pubmed/23476348 http://dx.doi.org/10.1107/S1600536812050404 Text en © Chiririwa and Davis 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Davis, Wade L.
Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title_full Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title_fullStr Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title_full_unstemmed Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title_short Chlorido{[(E)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κP}gold(I)
title_sort chlorido{[(e)-2-(diphenyl­phosphan­yl)benzyl­idene](furan-2-ylmeth­yl)amine-κp}gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588354/
https://www.ncbi.nlm.nih.gov/pubmed/23476348
http://dx.doi.org/10.1107/S1600536812050404
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