Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate

In the title solvate, [CuCl(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)CN, the Cu(I) ion is bonded to two triphenyl­phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP(2)SCl tetra­hedron. An intra­molecular N—H⋯Cl hydrogen bond, which closes...

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Detalles Bibliográficos
Autores principales: Wani, Kofsoh, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588355/
https://www.ncbi.nlm.nih.gov/pubmed/23476332
http://dx.doi.org/10.1107/S1600536812049537
Descripción
Sumario:In the title solvate, [CuCl(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)CN, the Cu(I) ion is bonded to two triphenyl­phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP(2)SCl tetra­hedron. An intra­molecular N—H⋯Cl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N—H⋯Cl hydrogen bonds and C—H⋯π inter­actions link the components, generating (110) layers.

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