Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate

In the title solvate, [CuCl(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)CN, the Cu(I) ion is bonded to two triphenyl­phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP(2)SCl tetra­hedron. An intra­molecular N—H⋯Cl hydrogen bond, which closes...

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Detalles Bibliográficos
Autores principales: Wani, Kofsoh, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588355/
https://www.ncbi.nlm.nih.gov/pubmed/23476332
http://dx.doi.org/10.1107/S1600536812049537
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author Wani, Kofsoh
Pakawatchai, Chaveng
Saithong, Saowanit
author_facet Wani, Kofsoh
Pakawatchai, Chaveng
Saithong, Saowanit
author_sort Wani, Kofsoh
collection PubMed
description In the title solvate, [CuCl(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)CN, the Cu(I) ion is bonded to two triphenyl­phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP(2)SCl tetra­hedron. An intra­molecular N—H⋯Cl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N—H⋯Cl hydrogen bonds and C—H⋯π inter­actions link the components, generating (110) layers.
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spelling pubmed-35883552013-03-08 Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate Wani, Kofsoh Pakawatchai, Chaveng Saithong, Saowanit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvate, [CuCl(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)CN, the Cu(I) ion is bonded to two triphenyl­phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP(2)SCl tetra­hedron. An intra­molecular N—H⋯Cl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N—H⋯Cl hydrogen bonds and C—H⋯π inter­actions link the components, generating (110) layers. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588355/ /pubmed/23476332 http://dx.doi.org/10.1107/S1600536812049537 Text en © Wani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wani, Kofsoh
Pakawatchai, Chaveng
Saithong, Saowanit
Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title_full Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title_fullStr Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title_full_unstemmed Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title_short Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) acetronitrile monosolvate
title_sort chlorido[1h-1,2,4-triazole-5(4h)-thione-κs]bis­(triphenyl­phosphane-κp)copper(i) acetronitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588355/
https://www.ncbi.nlm.nih.gov/pubmed/23476332
http://dx.doi.org/10.1107/S1600536812049537
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AT saithongsaowanit chlorido1h124triazole54hthioneksbistriphenylphosphanekpcopperiacetronitrilemonosolvate

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