Cargando…
(E)-3-Dimethylamino-1-(1,3-thiazol-2-yl)prop-2-en-1-one
In the title compound, C(8)H(10)N(2)OS, the 3-(dimethylamino)prop-2-en-1-one unit is approximately planar [give r.m.s. deviation] and the mean plane through the seven non-H atoms makes a dihedral angle of 8.88 (3)° with the thiazole ring. The carbonyl and ring C=N double bonds adjacent to the car...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588356/ https://www.ncbi.nlm.nih.gov/pubmed/23476405 http://dx.doi.org/10.1107/S1600536812048817 |
Sumario: | In the title compound, C(8)H(10)N(2)OS, the 3-(dimethylamino)prop-2-en-1-one unit is approximately planar [give r.m.s. deviation] and the mean plane through the seven non-H atoms makes a dihedral angle of 8.88 (3)° with the thiazole ring. The carbonyl and ring C=N double bonds adjacent to the carbonyl group are trans [N—C—C—O = 172.31 (15) °], while the conformation of the carbonyl and propene double bonds is cis [O—C—C—C = 2.2 (2)°]. In the crystal, short C—H⋯N and C—H⋯O interactions together with C—H⋯π interactions generate a three-dimensional network. |
---|