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2-(1-Phenyl-1H-benzimidazol-2-yl)phenol

In the title mol­ecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intra­mole...

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Autores principales: Thiruvalluvar, A., Rosepriya, S., Jayamoorthy, K., Jayabharathi, J., Öztürk Yildirim, Sema, Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588362/
https://www.ncbi.nlm.nih.gov/pubmed/23476443
http://dx.doi.org/10.1107/S1600536812049859
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author Thiruvalluvar, A.
Rosepriya, S.
Jayamoorthy, K.
Jayabharathi, J.
Öztürk Yildirim, Sema
Butcher, R. J.
author_facet Thiruvalluvar, A.
Rosepriya, S.
Jayamoorthy, K.
Jayabharathi, J.
Öztürk Yildirim, Sema
Butcher, R. J.
author_sort Thiruvalluvar, A.
collection PubMed
description In the title mol­ecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π–π stacking inter­actions, with a centroid–centroid distance of 3.8428 (12) Å.
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spelling pubmed-35883622013-03-08 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol Thiruvalluvar, A. Rosepriya, S. Jayamoorthy, K. Jayabharathi, J. Öztürk Yildirim, Sema Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π–π stacking inter­actions, with a centroid–centroid distance of 3.8428 (12) Å. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588362/ /pubmed/23476443 http://dx.doi.org/10.1107/S1600536812049859 Text en © Thiruvalluvar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thiruvalluvar, A.
Rosepriya, S.
Jayamoorthy, K.
Jayabharathi, J.
Öztürk Yildirim, Sema
Butcher, R. J.
2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title_full 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title_fullStr 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title_full_unstemmed 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title_short 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
title_sort 2-(1-phenyl-1h-benzimidazol-2-yl)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588362/
https://www.ncbi.nlm.nih.gov/pubmed/23476443
http://dx.doi.org/10.1107/S1600536812049859
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