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2-(1-Phenyl-1H-benzimidazol-2-yl)phenol
In the title molecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intramole...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588362/ https://www.ncbi.nlm.nih.gov/pubmed/23476443 http://dx.doi.org/10.1107/S1600536812049859 |
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author | Thiruvalluvar, A. Rosepriya, S. Jayamoorthy, K. Jayabharathi, J. Öztürk Yildirim, Sema Butcher, R. J. |
author_facet | Thiruvalluvar, A. Rosepriya, S. Jayamoorthy, K. Jayabharathi, J. Öztürk Yildirim, Sema Butcher, R. J. |
author_sort | Thiruvalluvar, A. |
collection | PubMed |
description | In the title molecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π–π stacking interactions, with a centroid–centroid distance of 3.8428 (12) Å. |
format | Online Article Text |
id | pubmed-3588362 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883622013-03-08 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol Thiruvalluvar, A. Rosepriya, S. Jayamoorthy, K. Jayabharathi, J. Öztürk Yildirim, Sema Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(19)H(14)N(2)O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by C—H⋯N and C—H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π–π stacking interactions, with a centroid–centroid distance of 3.8428 (12) Å. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588362/ /pubmed/23476443 http://dx.doi.org/10.1107/S1600536812049859 Text en © Thiruvalluvar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thiruvalluvar, A. Rosepriya, S. Jayamoorthy, K. Jayabharathi, J. Öztürk Yildirim, Sema Butcher, R. J. 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title | 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title_full | 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title_fullStr | 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title_full_unstemmed | 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title_short | 2-(1-Phenyl-1H-benzimidazol-2-yl)phenol |
title_sort | 2-(1-phenyl-1h-benzimidazol-2-yl)phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588362/ https://www.ncbi.nlm.nih.gov/pubmed/23476443 http://dx.doi.org/10.1107/S1600536812049859 |
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