Cargando…

2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate

In the 5-chloro­salicylate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is observed and the dihedral angle between the benzene ring and the –CO(2) group is 1.6 (6)°. In the crystal, the protonated N atom and the 2-a...

Descripción completa

Detalles Bibliográficos
Autores principales: Thanigaimani, Kaliyaperumal, Farhadikoutenaei, Abbas, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588363/
https://www.ncbi.nlm.nih.gov/pubmed/23476391
http://dx.doi.org/10.1107/S160053681205101X
_version_ 1782261548561989632
author Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description In the 5-chloro­salicylate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is observed and the dihedral angle between the benzene ring and the –CO(2) group is 1.6 (6)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O inter­actions, resulting in a layer parallel to (10-1).
format Online
Article
Text
id pubmed-3588363
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35883632013-03-08 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 5-chloro­salicylate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is observed and the dihedral angle between the benzene ring and the –CO(2) group is 1.6 (6)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O inter­actions, resulting in a layer parallel to (10-1). International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588363/ /pubmed/23476391 http://dx.doi.org/10.1107/S160053681205101X Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title_full 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title_fullStr 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title_full_unstemmed 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title_short 2-Amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
title_sort 2-amino-5-methyl­pyridinium 2-hy­droxy-5-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588363/
https://www.ncbi.nlm.nih.gov/pubmed/23476391
http://dx.doi.org/10.1107/S160053681205101X
work_keys_str_mv AT thanigaimanikaliyaperumal 2amino5methylpyridinium2hydroxy5chlorobenzoate
AT farhadikoutenaeiabbas 2amino5methylpyridinium2hydroxy5chlorobenzoate
AT arshadsuhana 2amino5methylpyridinium2hydroxy5chlorobenzoate
AT razakibrahimabdul 2amino5methylpyridinium2hydroxy5chlorobenzoate