Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate

The asymmetric unit of the title compound, [AuCl(C(31)H(32)NP)]·0.25CHCl(3), contains two independent complex mol­ecules and half a chloro­form solvent mol­ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P—Au...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588368/
https://www.ncbi.nlm.nih.gov/pubmed/23476336
http://dx.doi.org/10.1107/S1600536812049975
Descripción
Sumario:The asymmetric unit of the title compound, [AuCl(C(31)H(32)NP)]·0.25CHCl(3), contains two independent complex mol­ecules and half a chloro­form solvent mol­ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P—Au—Cl angles of 177.20 (4) and 178.54 (4)°.

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