Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate

The asymmetric unit of the title compound, [AuCl(C(31)H(32)NP)]·0.25CHCl(3), contains two independent complex mol­ecules and half a chloro­form solvent mol­ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P—Au...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Davis, Wade L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588368/
https://www.ncbi.nlm.nih.gov/pubmed/23476336
http://dx.doi.org/10.1107/S1600536812049975
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author Chiririwa, Haleden
Davis, Wade L.
author_facet Chiririwa, Haleden
Davis, Wade L.
author_sort Chiririwa, Haleden
collection PubMed
description The asymmetric unit of the title compound, [AuCl(C(31)H(32)NP)]·0.25CHCl(3), contains two independent complex mol­ecules and half a chloro­form solvent mol­ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P—Au—Cl angles of 177.20 (4) and 178.54 (4)°.
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spelling pubmed-35883682013-03-08 Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate Chiririwa, Haleden Davis, Wade L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [AuCl(C(31)H(32)NP)]·0.25CHCl(3), contains two independent complex mol­ecules and half a chloro­form solvent mol­ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P—Au—Cl angles of 177.20 (4) and 178.54 (4)°. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588368/ /pubmed/23476336 http://dx.doi.org/10.1107/S1600536812049975 Text en © Chiririwa and Davis 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Davis, Wade L.
Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title_full Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title_fullStr Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title_full_unstemmed Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title_short Chlorido{N-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κP}gold(I) chloro­form 0.25-solvate
title_sort chlorido{n-[2-(diphenyl­phosphan­yl)benzyl­idene]-2,6-diisopropyl­aniline-κp}gold(i) chloro­form 0.25-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588368/
https://www.ncbi.nlm.nih.gov/pubmed/23476336
http://dx.doi.org/10.1107/S1600536812049975
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AT daviswadel chloridon2diphenylphosphanylbenzylidene26diisopropylanilinekpgoldichloroform025solvate

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