Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc

In the mononuclear title complex, [ZnCl(2)(C(15)H(16)N(4)O)], the Zn(II) cation is five-coordinated in a strongly distorted square-pyramidal environment by two Cl(−) anions and a neutral tridentate Schiff base ligand. The Zn(II) cation is chelated by the carbonyl O atom, the imine N atom and the pyr...

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Autor principal: Chaur, Manuel N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588373/
https://www.ncbi.nlm.nih.gov/pubmed/23476326
http://dx.doi.org/10.1107/S1600536812049355
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author Chaur, Manuel N.
author_facet Chaur, Manuel N.
author_sort Chaur, Manuel N.
collection PubMed
description In the mononuclear title complex, [ZnCl(2)(C(15)H(16)N(4)O)], the Zn(II) cation is five-coordinated in a strongly distorted square-pyramidal environment by two Cl(−) anions and a neutral tridentate Schiff base ligand. The Zn(II) cation is chelated by the carbonyl O atom, the imine N atom and the pyridine N atom, which causes a slight loss of planarity for the ligand; the dihedral angle between the aromatic rings is 4.61 (8)°.
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spelling pubmed-35883732013-03-08 Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc Chaur, Manuel N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [ZnCl(2)(C(15)H(16)N(4)O)], the Zn(II) cation is five-coordinated in a strongly distorted square-pyramidal environment by two Cl(−) anions and a neutral tridentate Schiff base ligand. The Zn(II) cation is chelated by the carbonyl O atom, the imine N atom and the pyridine N atom, which causes a slight loss of planarity for the ligand; the dihedral angle between the aromatic rings is 4.61 (8)°. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588373/ /pubmed/23476326 http://dx.doi.org/10.1107/S1600536812049355 Text en © Manuel N. Chaur 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chaur, Manuel N.
Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title_full Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title_fullStr Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title_full_unstemmed Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title_short Dichlorido{(E)-4-dimethyl­amino-N′-[(pyri­din-2-yl)methyl­idene-κN]benzo­hydrazide-κO}zinc
title_sort dichlorido{(e)-4-dimethyl­amino-n′-[(pyri­din-2-yl)methyl­idene-κn]benzo­hydrazide-κo}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588373/
https://www.ncbi.nlm.nih.gov/pubmed/23476326
http://dx.doi.org/10.1107/S1600536812049355
work_keys_str_mv AT chaurmanueln dichloridoe4dimethylaminonpyridin2ylmethylideneknbenzohydrazidekozinc

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