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Bis(ethanamidinium) (1,10-phenanthroline-2,9-dicarboxylato)manganate(II) heptahydrate
In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cation...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588374/ https://www.ncbi.nlm.nih.gov/pubmed/23476314 http://dx.doi.org/10.1107/S1600536812048350 |
Sumario: | In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supramolecular structure is formed through N—H⋯O and O—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.553 (2) Å]. |
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