Cargando…

Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate

In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl­ate ligands in a distorted dodeca­hedral geometry. The double negative charge is balanced by two ethanamidinium cation...

Descripción completa

Detalles Bibliográficos
Autores principales: Miao, Yan-Li, Wang, Hong-Bo, Song, Wen-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588374/
https://www.ncbi.nlm.nih.gov/pubmed/23476314
http://dx.doi.org/10.1107/S1600536812048350
Descripción
Sumario:In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl­ate ligands in a distorted dodeca­hedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supra­molecular structure is formed through N—H⋯O and O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.553 (2) Å].