Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate

In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl­ate ligands in a distorted dodeca­hedral geometry. The double negative charge is balanced by two ethanamidinium cation...

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Detalles Bibliográficos
Autores principales: Miao, Yan-Li, Wang, Hong-Bo, Song, Wen-Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588374/
https://www.ncbi.nlm.nih.gov/pubmed/23476314
http://dx.doi.org/10.1107/S1600536812048350
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author Miao, Yan-Li
Wang, Hong-Bo
Song, Wen-Dong
author_facet Miao, Yan-Li
Wang, Hong-Bo
Song, Wen-Dong
author_sort Miao, Yan-Li
collection PubMed
description In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl­ate ligands in a distorted dodeca­hedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supra­molecular structure is formed through N—H⋯O and O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.553 (2) Å].
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spelling pubmed-35883742013-03-08 Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate Miao, Yan-Li Wang, Hong-Bo Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, (C(2)H(7)N(2))(2)[Mn(C(14)H(6)N(2)O(4))(2)]·7H(2)O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl­ate ligands in a distorted dodeca­hedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supra­molecular structure is formed through N—H⋯O and O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.553 (2) Å]. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588374/ /pubmed/23476314 http://dx.doi.org/10.1107/S1600536812048350 Text en © Miao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Yan-Li
Wang, Hong-Bo
Song, Wen-Dong
Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title_full Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title_fullStr Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title_full_unstemmed Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title_short Bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(II) hepta­hydrate
title_sort bis(ethanamidinium) (1,10-phen­an­thro­line-2,9-dicarboxyl­ato)manganate(ii) hepta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588374/
https://www.ncbi.nlm.nih.gov/pubmed/23476314
http://dx.doi.org/10.1107/S1600536812048350
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AT wanghongbo bisethanamidinium110phenanthroline29dicarboxylatomanganateiiheptahydrate
AT songwendong bisethanamidinium110phenanthroline29dicarboxylatomanganateiiheptahydrate

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