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Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2) O (1):O (1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu)
In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitrogen and the other Cu(II) ato...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588377/ https://www.ncbi.nlm.nih.gov/pubmed/23476320 http://dx.doi.org/10.1107/S1600536812049410 |
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author | Wang, Jing-lin Wang, Cai-rong Wang, Zhi-jun Yang, Bin-sheng |
author_facet | Wang, Jing-lin Wang, Cai-rong Wang, Zhi-jun Yang, Bin-sheng |
author_sort | Wang, Jing-lin |
collection | PubMed |
description | In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitrogen and the other Cu(II) atom are located in apical positions. The whole molecule looks like a paddle-wheel. In the crystal, chains are assembled along the b axis through C—H⋯O hydrogen bonds and slipped π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.6929 (3) Å and slippage = 0.641 (1) Å]. |
format | Online Article Text |
id | pubmed-3588377 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883772013-03-08 Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2) O (1):O (1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) Wang, Jing-lin Wang, Cai-rong Wang, Zhi-jun Yang, Bin-sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitrogen and the other Cu(II) atom are located in apical positions. The whole molecule looks like a paddle-wheel. In the crystal, chains are assembled along the b axis through C—H⋯O hydrogen bonds and slipped π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.6929 (3) Å and slippage = 0.641 (1) Å]. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588377/ /pubmed/23476320 http://dx.doi.org/10.1107/S1600536812049410 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Jing-lin Wang, Cai-rong Wang, Zhi-jun Yang, Bin-sheng Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2) O (1):O (1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title | Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
O
(1):O
(1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title_full | Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
O
(1):O
(1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title_fullStr | Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
O
(1):O
(1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title_full_unstemmed | Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
O
(1):O
(1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title_short | Tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
O
(1):O
(1′)]bis[(acetonitrile-κN)copper(II)](Cu—Cu) |
title_sort | tetrakis[μ-2-(methoxycarbonyl)benzoato-κ(2)
o
(1):o
(1′)]bis[(acetonitrile-κn)copper(ii)](cu—cu) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588377/ https://www.ncbi.nlm.nih.gov/pubmed/23476320 http://dx.doi.org/10.1107/S1600536812049410 |
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