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Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)

In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitro­gen and the other Cu(II) ato...

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Autores principales: Wang, Jing-lin, Wang, Cai-rong, Wang, Zhi-jun, Yang, Bin-sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588377/
https://www.ncbi.nlm.nih.gov/pubmed/23476320
http://dx.doi.org/10.1107/S1600536812049410
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author Wang, Jing-lin
Wang, Cai-rong
Wang, Zhi-jun
Yang, Bin-sheng
author_facet Wang, Jing-lin
Wang, Cai-rong
Wang, Zhi-jun
Yang, Bin-sheng
author_sort Wang, Jing-lin
collection PubMed
description In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitro­gen and the other Cu(II) atom are located in apical positions. The whole mol­ecule looks like a paddle-wheel. In the crystal, chains are assembled along the b axis through C—H⋯O hydrogen bonds and slipped π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.6929 (3) Å and slippage = 0.641 (1) Å].
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spelling pubmed-35883772013-03-08 Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu) Wang, Jing-lin Wang, Cai-rong Wang, Zhi-jun Yang, Bin-sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear copper(II) title complex, [Cu(2)(C(9)H(7)O(4))(4)(C(2)H(3)N)(2)], an inversion centre is situtated at the mid-point of the Cu—Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitro­gen and the other Cu(II) atom are located in apical positions. The whole mol­ecule looks like a paddle-wheel. In the crystal, chains are assembled along the b axis through C—H⋯O hydrogen bonds and slipped π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.6929 (3) Å and slippage = 0.641 (1) Å]. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588377/ /pubmed/23476320 http://dx.doi.org/10.1107/S1600536812049410 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jing-lin
Wang, Cai-rong
Wang, Zhi-jun
Yang, Bin-sheng
Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title_full Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title_fullStr Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title_full_unstemmed Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title_short Tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) O (1):O (1′)]bis­[(acetonitrile-κN)copper(II)](Cu—Cu)
title_sort tetra­kis[μ-2-(meth­oxy­carbon­yl)benzoato-κ(2) o (1):o (1′)]bis­[(acetonitrile-κn)copper(ii)](cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588377/
https://www.ncbi.nlm.nih.gov/pubmed/23476320
http://dx.doi.org/10.1107/S1600536812049410
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