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Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)

In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octa­hedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,...

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Autores principales: Gueddar, Hicham, Bouhfid, Rachid, Essassi, El Mokhtar, El Brahmi, Nabil, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588380/
https://www.ncbi.nlm.nih.gov/pubmed/23476345
http://dx.doi.org/10.1107/S1600536812048751
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author Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
El Brahmi, Nabil
El Ammari, Lahcen
author_facet Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
El Brahmi, Nabil
El Ammari, Lahcen
author_sort Gueddar, Hicham
collection PubMed
description In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octa­hedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co(II) atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thia­zole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole mol­ecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network.
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spelling pubmed-35883802013-03-08 Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II) Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar El Brahmi, Nabil El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octa­hedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co(II) atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thia­zole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole mol­ecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588380/ /pubmed/23476345 http://dx.doi.org/10.1107/S1600536812048751 Text en © Gueddar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
El Brahmi, Nabil
El Ammari, Lahcen
Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title_full Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title_fullStr Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title_full_unstemmed Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title_short Bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
title_sort bis[1-benzyl-2-(1,3-thia­zol-4-yl)-1h-benzimidazole-κ(2) n (2),n (3)]dichloridocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588380/
https://www.ncbi.nlm.nih.gov/pubmed/23476345
http://dx.doi.org/10.1107/S1600536812048751
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