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Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II)
In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588380/ https://www.ncbi.nlm.nih.gov/pubmed/23476345 http://dx.doi.org/10.1107/S1600536812048751 |
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author | Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar El Brahmi, Nabil El Ammari, Lahcen |
author_facet | Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar El Brahmi, Nabil El Ammari, Lahcen |
author_sort | Gueddar, Hicham |
collection | PubMed |
description | In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co(II) atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thiazole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole molecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-3588380 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35883802013-03-08 Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II) Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar El Brahmi, Nabil El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(17)H(13)N(3)S)(2)], the Co(II) atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co(II) atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thiazole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole molecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588380/ /pubmed/23476345 http://dx.doi.org/10.1107/S1600536812048751 Text en © Gueddar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar El Brahmi, Nabil El Ammari, Lahcen Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2) N (2),N (3)]dichloridocobalt(II) |
title | Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]dichloridocobalt(II) |
title_full | Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]dichloridocobalt(II) |
title_fullStr | Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]dichloridocobalt(II) |
title_full_unstemmed | Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]dichloridocobalt(II) |
title_short | Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]dichloridocobalt(II) |
title_sort | bis[1-benzyl-2-(1,3-thiazol-4-yl)-1h-benzimidazole-κ(2)
n
(2),n
(3)]dichloridocobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588380/ https://www.ncbi.nlm.nih.gov/pubmed/23476345 http://dx.doi.org/10.1107/S1600536812048751 |
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