2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione

The whole molecule of the title compound, C(17)H(21)NO(2), is generated by twofold rotational symmetry. The N atom and the C and H atoms in position 4 of the pyridine ring lie on the twofold axis. The cyclohexene ring has a sofa conformation with the CH(2) C atom adjacent to the dimethyl-substituted...

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Autores principales: Öztürk Yildirim, Sema, Butcher, Ray J., Şimsek, Rahime, El-Khouly, Ahmed, Şafak, Cihat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588388/
https://www.ncbi.nlm.nih.gov/pubmed/23476469
http://dx.doi.org/10.1107/S1600536812048957
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author Öztürk Yildirim, Sema
Butcher, Ray J.
Şimsek, Rahime
El-Khouly, Ahmed
Şafak, Cihat
author_facet Öztürk Yildirim, Sema
Butcher, Ray J.
Şimsek, Rahime
El-Khouly, Ahmed
Şafak, Cihat
author_sort Öztürk Yildirim, Sema
collection PubMed
description The whole molecule of the title compound, C(17)H(21)NO(2), is generated by twofold rotational symmetry. The N atom and the C and H atoms in position 4 of the pyridine ring lie on the twofold axis. The cyclohexene ring has a sofa conformation with the CH(2) C atom adjacent to the dimethyl-substituted C atom displaced by 0.5949 (16) Å from the mean plane of the other five C atoms. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into chains parallel to the a axis. In addition, π–π stacking inter­actions [centroid–centroid distance = 3.8444 (7) Å] contribute to the stabilization of the crystal structure.
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spelling pubmed-35883882013-03-08 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione Öztürk Yildirim, Sema Butcher, Ray J. Şimsek, Rahime El-Khouly, Ahmed Şafak, Cihat Acta Crystallogr Sect E Struct Rep Online Organic Papers The whole molecule of the title compound, C(17)H(21)NO(2), is generated by twofold rotational symmetry. The N atom and the C and H atoms in position 4 of the pyridine ring lie on the twofold axis. The cyclohexene ring has a sofa conformation with the CH(2) C atom adjacent to the dimethyl-substituted C atom displaced by 0.5949 (16) Å from the mean plane of the other five C atoms. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into chains parallel to the a axis. In addition, π–π stacking inter­actions [centroid–centroid distance = 3.8444 (7) Å] contribute to the stabilization of the crystal structure. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588388/ /pubmed/23476469 http://dx.doi.org/10.1107/S1600536812048957 Text en © Öztürk Yildirim et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Öztürk Yildirim, Sema
Butcher, Ray J.
Şimsek, Rahime
El-Khouly, Ahmed
Şafak, Cihat
2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title_full 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title_fullStr 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title_full_unstemmed 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title_short 2,2,7,7-Tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
title_sort 2,2,7,7-tetra­methyl-1,2,3,4,5,6,7,8-octa­hydro­acridine-1,8-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588388/
https://www.ncbi.nlm.nih.gov/pubmed/23476469
http://dx.doi.org/10.1107/S1600536812048957
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