Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)

In the title compound, [Co(C(10)H(8)N(2))(3)](PF(6))(2), the Co(II) atom is coordinated by the six N atoms of three 2,2′-bipyridyl ligands and adopts a highly distorted octa­hedral geometry. The crystal used was a merohedral twin, the refined ratio of twin components being 0.820 (1):0.180 (1). The c...

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Detalles Bibliográficos
Autores principales: Menteş, Ayfer, Singh, Kuldip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588389/
https://www.ncbi.nlm.nih.gov/pubmed/23476351
http://dx.doi.org/10.1107/S1600536812050234
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author Menteş, Ayfer
Singh, Kuldip
author_facet Menteş, Ayfer
Singh, Kuldip
author_sort Menteş, Ayfer
collection PubMed
description In the title compound, [Co(C(10)H(8)N(2))(3)](PF(6))(2), the Co(II) atom is coordinated by the six N atoms of three 2,2′-bipyridyl ligands and adopts a highly distorted octa­hedral geometry. The crystal used was a merohedral twin, the refined ratio of twin components being 0.820 (1):0.180 (1). The crystal structure features weak C—H⋯F inter­actions, forming a three-dimensional network.
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spelling pubmed-35883892013-03-08 Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate) Menteş, Ayfer Singh, Kuldip Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(8)N(2))(3)](PF(6))(2), the Co(II) atom is coordinated by the six N atoms of three 2,2′-bipyridyl ligands and adopts a highly distorted octa­hedral geometry. The crystal used was a merohedral twin, the refined ratio of twin components being 0.820 (1):0.180 (1). The crystal structure features weak C—H⋯F inter­actions, forming a three-dimensional network. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588389/ /pubmed/23476351 http://dx.doi.org/10.1107/S1600536812050234 Text en © Menteş and Singh 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Menteş, Ayfer
Singh, Kuldip
Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title_full Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title_fullStr Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title_full_unstemmed Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title_short Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis­(hexa­fluoridophosphate)
title_sort tris(2,2′-bipyridine-κ(2) n,n′)cobalt(ii) bis­(hexa­fluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588389/
https://www.ncbi.nlm.nih.gov/pubmed/23476351
http://dx.doi.org/10.1107/S1600536812050234
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