catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]

In the title coordination polymer, {[Li(C(2)H(5)NO(2))(2)(H(2)O)]Br}(n), the Li(+) cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring comple...

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Detalles Bibliográficos
Autores principales: Balakrishnan, T., Ramamurthi, K., Jeyakanthan, J., Thamotharan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588392/
https://www.ncbi.nlm.nih.gov/pubmed/23476353
http://dx.doi.org/10.1107/S1600536812050660
Descripción
Sumario:In the title coordination polymer, {[Li(C(2)H(5)NO(2))(2)(H(2)O)]Br}(n), the Li(+) cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring complexes, forming an infinite chain parallel to the c axis. Polymeric chains are further linked by extensive hydrogen bonds involving the Br(−) anions and glycine and water mol­ecules, producing a three-dimensional network.

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